Broadcast live, the four-hour show will feature elaborate acts of wooden and metal bondage.
DeviceBondage.com director Cyd Black praised the two performers.
"The great thing about Samantha is that you can do a lot of really sexual stuff with her," Black said. "So there'll be a whole lot of intensely sexual bondage, as opposed to pain. Samantha's a really hot model and she's going to be tied up every which way."
DeviceBondage.com representatives said that Sin's appeal lies in the combination of her natural looks and primarily vanilla performance background. Black promised, though, that Sin would explore the boundaries of her personal fears.
"That means I'll probably put her in some small spaces," Black said referring to an earlier admission from Sin that she disliked such predicaments.
Vale has performed for DeviceBondage.com twice before. The show begins at noon on Saturday.