Adams, who is featured on the cover of the release, performs her first anal scene with male performer Michel Stefano.
Adams, Hustler magazine's November 2009 cover girl and centerfold, said she waited for the right time and the right director for her anal video debut.
"This is something my fans have wanted to see for a long time," she added. "But I wanted to make sure it's something they'll enjoy and that it won't be just another forgettable scene.”
The title was directed by award winning gonzo director Mason.
"Mason is an amazing director and I've always been a fan of hers,” Adams said. “She brought the intensity she's known for and I know the fans will enjoy this movie for a long time.”
“Massive Asses 5” hits stores May 11.